IN-TEXT QUESTIONS SOLVEDNCERT TEXTBOOK PAGE 321.  In a reaction 5.3 g of sodium carbonate reacted with 6 g of ethanoic acid. The products were 2.2 g of carbon dioxide, 0.9 g water and 8.2 g of sodium ethanoate. Show that these observations are in agreement with the law of conservation of mass carbonate.Ans.

 Sodium carbonate + Ethanoic acid → Sodium ethanoate + Carbon dioxide + Water 5.3 g + 6 g → 8.2 g + 2.2 g + 0.9 g

LHS                        RHS        11.3 g        =        11.3 g        (Mass of reactant) (Mass of product)        This shows, that during a chemical reaction mass of reactact = mass of product.2.  Hydrogen and oxygen combine in the ratio of 1 : 8 by mass to form water. What mass of oxygen gas would be required to react completely with 3 g of hydrogen gas?Ans. Ratio of H : O by mass in water is:        Hydrogen : Oxygen → H2O        1 : 8 = 3 : x        x = 8 × 3        ∴ 24 g of oxygen gas would be required to react completely with 3 g of hydrogen gas.3.  Which postulate of Dalton’s atomic theory the result of the law of conservation of mass?Ans. The postulate of Dalton’s atomic theory that is the result of the law of conservation of mass is-the relative number and kinds of atoms are constant in a given compound. Atoms cannot be created nor destroyed in a chemical reaction.4.  Which postulate of Dalton’s atomic theory can explain the law of definite proportions?Ans. The relative number and kinds of atoms are constant in a given compound.NCERT TEXTBOOK PAGE 351.  Define the atomic mass unit.Ans. One atomic mass unit is equal to exactly one-twelfth (1/12th) the mass of one atom of carbon-12. The relative atomic masses of all elements have been found with respect to an atom of carbon-12.2.  Why is it not possible to see an atom with naked eyes?Ans. Atom is too small to be seen with naked eyes. It is measured in nanometres.1 m = 109 nmNCERT TEXTBOOK PAGE 351.  Write down the formulae of        (i)   Sodium oxide        (ii)  Aluminium chloride        (iii) Sodium sulphide        (iv) Magnesium hydroxideAns. The formulae. are         (i)   Formula bf Sodium Oxide                Symbol → Na                O                Charge → +1                –2                Formula → Na2O         (iii) Formula of Sodium Oxide                Symbol → Na                S                Charge → + 1                –2                Formula → Na2S         (ii) Formula of aluminium chloride                Symbol → Al                Cl                Charge → +3                –1                Formula → A1C13         (iv) Formula of magnesium hydroxide                Symbol → Mg                OH                Charge                1                Formula → Mg(OH)22.  Write down the names of compounds represented btthe following formulae:      (i) Al2(SO4)3                  (ii) CaCl2                  (iii) K2SO4                  (iv) KNO3      (v) CaCO3Ans. (i) A12(SO4)3                  → Aluminium sulphate         (ii) CaC12                        → Calcium chloride         (iii) K∴SO4                     → Potassium sulphate         (iv) KNO3                       → Potassium nitrate         (v) CaCO3                      → Calcium carbonate3.  What is meant by the term chemical formula?Ans. The chemical formula of the compound is a symbolic representation of its composition, e.g., chemical formula of sodium chloride is NaCl.4.  How many atoms are present in a      (i) H2S molecule and      (ii) PO43– ion?Ans. (i) H2S → 3 atoms are present         (ii) PO43– → 5 atoms are presentNCERT TEXTBOOK PAGE 401.  Calculate the molecular masses of H2, O2, C12, CO2, CH4, C2H6, C2H4, NH3, CH3OH.Ans. The molecular masses are:          H2 ⇒ 1 × 2 → 2u          O2⇒ 16 × 2 → 32u          Cl2 ⇒ 35.5 × 2 → 71 u          CO2 ⇒ 1 × 12 + 2 × 16 = 12 +32 = 44 u          CH4 ⇒ 1 × 12 + 4 × 1 = 16 u          C2H6 ⇒�n2 × 12 + 6 × 1 = 30 u          C2H4 ⇒ (2 × 12) + (4 × 1) = 28 u          NH3 ⇒ (1 × 14) + (3 × 1) = 17 u          CH3OH ⇒ 12 + (3 × 1) + 16 + 1 = 32 u2.  Calculate the formula unit masses of ZnO, Na2O, K2Co3 given atomic masses of Zn=65 u, Na = 23 u, K = 39 u, C = 12u, and O = 16 u.Ans. The formula unit mass of          (i) ZnO = 65 u + 16 u =.81 u          (ii) Na2O = (23 u × 2) + .16 u : = 46u+ 161.u.               = 62 u          (iii) K2CO3 = (39 u × 2) + 12 u + 16 u × 3          = 75 u + 12u = 48u = 138uNCERT TEXTBOOK PAGE 421.  If one mole of carbon atoms weigh 12 grams, what is the mast (in grams) of 1 atom of carbon?Ans. 1 mole of carbon atoms 6.022 × 1023 atoms = 12 g          Mass of 1 atom = ?          ∴ Mass of 1 atom of carbon

=1.99 × 10–23 g2.  Which has more number of atoms, 100 grams of sodium or 100 grams of iron (given atomic mass of Na = 23 u, Fe = 56 u)?Ans. 23 g of Na = 6.022 × 1023 atoms (1 mole).          100 g of Na = ?

= 26.182 ×1023 = 2.6182×1024 atoms          56 g of Fe = 6.022 × 1023 atoms          100 g o Fe = ?          100 g of Na contain → 2.618 × 1024 atoms          100 g of Fe contain → 1.075 × 1024 atoms          ∴ 100 g of Na contains more atoms.QUESTIONS FROM NCERT TEXTBOOK1.  A 0.24 g sample of compound of oxygen and boron was found by analysis to contain 0.096 g of boron and 0.144 g of oxygen. Calculate the percentage composition of the compound by weight.Ans. Boron and oxygen compound → Boron + Oxygen          0.24 g → 0:096g + 0.144g          Percentage composition of the compound          For boron: 0.24g → 0.096 g          100 g → ?

For oxygen:          0.24 g → 0.144 g of oxygen          100 g → ?

2.  When 3.0 g of carbon is burnt in 8.00 g oxygen; 11.00 g of carbon dioxide is produced. What mass of carbon dioxide will formed when. 3.00 g of carbon is burnt in 50.00 g of oxygen? Which law of chemicai combination will govern your answer?Ans. The reaction of burning of carbon in oxygen may be written as:

It shows that 12 g of carbon burns in 32 g oxygen to form 44 g of carbon dioxide. Therefore 3 g of carbon reacts with 8 g of oxygen to form 11 g of carbon dioxide. It is given that 3.0 g of carbon is burnt with 8 g of oxygen to produce 11.0 g of CO2. Consequently 11.0 g of carbon dioxide will be formed when 3.0 g of C is burnt in 50 g of oxygen consuming 8 g of oxygen, leaving behind 50 �V 8 = 42 g of 02. The answer governs the law of constant proportion.3.  What are polyatomic ions? Give eaamples:Ans. The ions which contain more than one atoms (same kind or may be of different kind) and behave as a single unit are called polyatomic ions e.g., OH, SO2–4, CO32–.4.  Write the chemical formulae of the following:       (a) Magnesium chloride              (b) Caldum oxide       (c) Copper nitrate                          (d) Aluminium chloride       (e) Calcium carbonate.Ans. (a) Magnesium chloride                Symbol →                    Mg Cl                Change →                    +2 –1                Formula →                    MgCl2       (b) Calcium oxide                Symbol →                    Ca O                Charge →                    +2 –2                Formula →                    CaO       (c) Copper nitrate                Symbol →                    Cu NO3                Change →                    +2 –1                Formula → Cu(NO3)2       (d) Aluminium chloride                Symbol →                    Al Cl                Change →                    +3 –1                Formula →                    A1Cl3       (d) Calcium carbonate                Symbol →                    Ca CO3                Change →                    +2 –2                Formula →                    CaCO35.  Give the names of the elements present in the following compounds:       (a) Quick time                                     (b) Hydrogen bromide       (c) Baking powder                            (d) Potassium sulphate.Ans. (a) Quick lime → Calcium oxide                  Elements → Calcium and oxygen         (b) Hydrogen bromide                  Elements → Hydrogen and bromine         (c) Baking powder → Calcium hydrogen carbonate                  Elements → Calcium, hydrogen, carbon and oxygen         (d) Potassium sulphate                  Elements → Potassium, sulphur and oxygen6.  Calculate the molar mass of the following substances.       (a) Ethyne, C2H2       (b) Sulphur molecule, S8       (c) Phosphorus molecule, P4 (Atomic mass of phosphorus = 31)       (d) Hydrochloric acid, HCl       (e) Nitric acid, HNO3Ans. The molar mass of the following: [Unit is ‘g’]       (a) Ethyne, C2H2 = 2 × 12 + 2 × 1 = 24 + 2 = 26 g       (b) Sulphur molecule, S8 = 8 × 32 = 256 g       (c) Phosphorus molecule, P4 = 4 × 31 = 124 g       (d) Hydrochloric acid, HCl = 1 × 1 + 1 × 35.5                = 1 + 35.5 = 36.5 g       (e) Nitric acid, HNO3 = 1 × 1 + 1 × 14 + 3 × 16                = 1 + 14 + 48 = 63 g7.  What is the mass of       (a) 1 mole of nitrogen atoms?       (b) 4 moles of aluminium atoms       (c) 10 moles of sodium sulphite (Na2SO3)?Ans. (a) Mass of 1 mole of nitrogen atoms = 14g          (b) 4 moles of aluminium atoms                Mass of 1 mole of aluminium atoms = 27 g          Mass of 4 moles of aluminium atoms = 27 × 4 = 108 g          (c) 10 moles of sodium sulphite (Na2SO3)                Mass of 1 mole of Na2SO3 = 2 × 23 + 32 + 3 ×16                =46 + 32 + 48 = 126 g                Mass of 10 moles of Na2SO3 = 126 × 10                = 1260 g8.  Convert into mole.       (a) 12 g of oxygen gas       (b) 20 g of water       (c) 22 g of Carbon dioxide.Ans. (a) Given mass of oxygen gas = 12 g                Molar mass of oxygen gas (O2) = 32 g                Mole of oxygen gas 12

mole       (b) Given mass of water = 20 g                Molar mass of water (H2O) = (2 × 1) + 16 = 18 g                Mole of water

mole       (c) Given mass of Carbon dioxide = 22 g                Molar mass of carbon dioxide (CO2) = (1 × 12) + (2 × 16)                = 12 + 32 = .44 g                Mole of carbon dioxide

mole9.  What is the mass of       (a) 0.2 mole of oxygen atoms?       (b) 0.5 mole of water molecules?Ans. (a) Mole of Oxygen atoms = 0.2 mole                Molar mass of oxygen atoms = 16 g                Mass of oxygen atoms = 16 × 0.2 = 3.2 g       (b) Mole of water molecule = 0.5 mole                Molar mass of water molecules = 2 × 1 + 16 = 18 g                Mass of H2O = 18 × 0.5 = 9 g10.  Calculate the number of molecules of sulphur (S8) present in 16 g of solid sulphur.Ans. Molar mass of S8 sulphur = 256 g = 6.022 × 1023 molecule                Given mass of sulphur = 16 g

= 0.376 × 1023                = 3.76 × 1022 molecules11.  Calculate the number of aluminium ions present in 0.051 g of aluminium oxide.Ans. Molar mass of aluminium oxide Al2O3                = (2 × 27) + (3 × 16)                = 54 + 48 = 102g.                102 g of Al2O3 contains = 2 × 6.022 × 1023 aluminium ions

= 0.006022 × 1023                = 6.022 × 1020 Al3+ ions